Hello Tongphan, if the problem started when you adding the Ca reactor. Do you any Co2 defuser container? My suggestion is drip your effluent into a cup with an air stone to evap the CO2 before it get into your tank. Does it make any sense? You can go to any LFS and buy the square plastic container the kind they use to catch the fish. Drill a hole on the side of the container, get a plastic cup make sure it fit inside the container and also drill a hole toward the top.
Get yourself an air pump and air stone. Put it inside the cup and drip your effluent into the cup. one you do that, test your Ph in the container chamber (not in the cup). You will notice the pH change due the the CO2 being reduce and pH will read higher.
My effluent coming out of the Ca reactor read 6.7 and 8.1 after the defuser.... If you need any help, feel free to drop me a call... Thanks