pH is interesting because if we choose, it can be monitored closely via pH probes like apex provides. However, not sure how significant it is. It can be effected by opening or closing Windows. Also seems that with our alkalinity that our water should be reasonably buffered but this is where my lack of chemistry knowledge tends to get me in trouble and out of my comfort zone.
I'm not sure I know anyone that tries to manage pH either. I use my apex pH probe but I never calibrated it, I simply look for fluctuation range which seems about 0.2-0.25 units through 24 hour cycle