Fedex by far, and I've used them all except for ups which is known to be pretty crappy for overnight.
I'm currently putting together a lawsuit for DHL, they will literally scam you. They'd delivery shipments 3-4 days later and claim that it never happened, deliver shipments to the wrong city and leave them a random house and claim that it never happened, and they'd have their online department illegally edit tracking info to say that it had been shipped regular overnight instead of priority so that they wouldn't have to refund for any shipments that arrived after 10:30am.
Long story short, don't use dhl.