Even with powerheads turned off or down the circulation pump is still running as is the skimmer, so there's plenty of gas exchange in the entire system of water. And yes, the whole system is synthesized compared to a natural ocean reef.
The sicce controller is a fussy thing, you have to set it into night mode when you want it to repeat every 24 hours, night mode has a 8 hour duration. There have been times were it got reset and then not working so the heads alternate their normal 35-40 seconds on each powerhead, I have the 1150gph ones in a 75. They move plenty of water and the fishe and corals don't seem to mind either way, day or night. If they want a eddy they find one. It sure moves a lot of water around though. The cuc know where the eddies are and gather there to clean up. My rocks are suspended on an acrylic rod platform so water flows under them too.